If everything is working correctly; thermostat, heater core, water pump, head gaskets, etc. Then that leaves the radiator cap, the overflow hose or the overflow tank as being the problem.
As the engine heats up the coolant expands flowing into the overflow tank. As the engine cools the coolant is drawn back into the engine from the overflow tank. but this depends on the vacuum created by the cooling liquid. the radiator cap has a "valve" that lets pressure out and vacuum in. If it fails then you may not achieve a good vacuum. The hose that connects to the over flow tank must be non leaking as well; if it leaked then coolant would not be drawn back into the engine, only air would be sucked in. And lastly the coolant has to be drawn from the bottom of the overflow tank. again we dont want to be sucking air.
Some engines require a vent screw to be opened when bleeding the air out of the engine.
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