First off refrigerators dont use ammonia. A gas detector like you may have probably uses catalytic response to detect flammable vapors. These detectors are the least expensive. If you have ammonia that is used for fertilizer like farmers use, it may detect it because anhydrous ammonia is combustible. (not flammable). Ammonia has a very strong odor though and that should be your first indication of a leak in an ammonia system. Ammonia that is used for cleaning does not have the same properties as the industrial ammonia that is used in other applications. Therefore it will not be detected.
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