When starting my honda accord 2010 v6 model a loud knocking noise has commenced.once engine is warm it stops.

SOURCE: 2002 jeep liberty siren whining noise on start up

I had the same problem at about the same mileage. Replaced the power steering pump and the start up screaming went away! ( The Jeep's and mine!)

SOURCE: Mazda MPV V6 engine noise

My strong guess without looking at it would be a cracked exhaust manifold, when it gets hot the metal expands an it doesn't leak.

SOURCE: 2001 Grand Caravan Loud Knocking Noise

big end or main bearing.

SOURCE: engine or transmission knock / rattle upon

I had the same problem on my 2006 Lucerne and it was the engine mount located on the front of the vehicle behind the radiator.

SOURCE: Engine make Knocking noise when cold

I have the same problem on my 2.0L 2001 Legacy auto. It began about 1000 miles ago. It has now done 84k. From my online searches this is most probably 'piston slap', and is not serious. To save weight Subaru shaved down the skirts on the pistons. With normal engine wear the pistons will at some point rattle against the cylinders until the engine is heated up and the pistons expand. The rattling should go away after a few minutes. If it persists say 10-15 minutes, it may be another problem.