HiClick on this link and it will explain what AOSS is.
http://wiki.answers.com/Q/Where_is_the_aoss_button_located_on_ps3#ixzz1PCR4GssJ
There is no physical aoss button on the PS3.
On your PS3 XMB navigate to: Settings -> Network Settings -> Internet Connection Setting -> Custom Method - Wireless- (WLAN Setting) Auto - AOSS
Your router will have a button for you unless it does not which means that it does not have the ability to use aoss. When you select aoss on your xmb, your ps3 will notify you when to push this button on your router and you have two minutes to do so.
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