02 sensor was least likely over your problems. Likely a faulty injector, plug, wire, etc. Zero in on cylinder doing miss. Pull one plug wire and start car. If it runs worse you still don't have correct one. Keep going till there is no change when running.
Oxygen sensor only report the condition of the engine the rough running condition can range from a worn sparkplug wires to worn sparkplugs to valve problems to injector problems. with the cadillac deville a tune up should be the first attempt to smooth the rough idle with the inspection of the cap and rotor cap and rotor do have a tendancy to arc internally and create misfire so does sparkplug wire that can leak spark voltage to ground and create misfire. the spark plug wire especially if they are brittle and hard can create issues
http://howtobyme.blogspot.com/2011/12/car-still-runs-rough-after-tune-up.html
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2006 kia rio runs rough
http://technoanswers.blogspot.com/2012/10/2006-kia-rio-runs-rough.html
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Idle flair is noticed on car? Rough idle? car will not idle?
Erratic idle speed?
http://technoanswers.blogspot.in/2012/02/idle-flair-is-noticed-on-car-rough-idle.html
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Rough idle, staling and Erratic shifting?
http://technoanswers.blogspot.in/2012/03/rough-idlestaling-and-erratic-shifting.html
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These details will help.
Thanks.
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