Hi
This sounds very much to me like a power supply problem.
If I understand your question correctly, the radio will turn on but when transmitting it shuts itself shuts off. This is usually caused by a poor connection to your battery. Although it is possible to show 12v using a voltmeter, there may not be enough connection when putting the circuit under load. (25 watts is a considerable load)
I would inspect both positive and negative connections (pay particular attention to the crimped lugs) , clean and lubricate them and give it another shot.
Here is a link to Trojan battery explaining in detail the importance of clean battery terminals.
Hope this helps you out.
-Steve
http://www.trojanbattery.com/pdf/WP_BatteryCableGuide_0512.pdf
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