If you are concerned with toxic products and damage to the tub and tiles, here's a "natural" solution. Peel off a few oranges and stuff the peels in a sealable jar(like a mason jar). Add vinegar to near the top and seal the jar. Let it sit for 2 weeks on your shelf. Open and use on stains. Works really good and not poisonous.
Let me know if it worked for you. P.S. You can use other citrus peels too, like pineapple etc.... Good luck.
SOURCE: blue grout spilled on tub while installing tile above the tub
Try 50:50 bleach and water with a green scrubber pad.
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