Which is more potent"
Milligrams are abbreviated mg, and micrograms are sometimes abbreviated mcg.
A milligram has 1000 times as much mass as a microgram.
Without more details on the mixture, there is no way to tell you about potency. Potency is usually measured in parts per million, or ppm. You would need two different substances to compare in order to come up with the potency of that solution.
If this is actually a drug question, as an "experienced" person, I suggest erowid.org for good information, and that you should know much more info than some rando on the internet can tell you in a chat box, before you go adventuring.
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