If it smells like burning then its oil....if its scentless its water. Depends whether it disappears when engine is warmed up and what the outside temperature is.
In the morning,it is quite common for some white smoke to appear due to the difference in temperature of the outside and the heat of the engine,but should stop after warming up.If there is excessive smoke,there could be more wrong,possibly a blown head gasket.Try having a pressure check done on the cooling system as well as a compression test done on the cylinders.
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