Did you check the Vacuum lines to the Secondary air Valve Controls. They may be rotten. Can you do a Smoke test. Replace dry rotted lines with either 3/16 Fuel or Power Steering Hoses if you do not get ORM Vacuum lines/hoses. There are many Vedios on You Tube showing this specific problem solving on German cars. you can check out these,
Secondary Air Injection Systems on German Vehicles
E39) 2001 BMW 525i Resolve P0491/P0492 for less than $2.00 in approx 15min.
How to Fix and Diagnose BMW P0491 P0492 Secondary Air / Vacuum Leak E36 E46 E39 E53
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