Not a Peugeot expert, but it sounds like you are not keeping the radio memory alive when the key is off. Usually there is a circuit to the radio that is hot with the key off that keeps the memory for stations etc.
Sometimes this is the same circuit for interior lights or cig lighter.
SOURCE: peugeot 206 radio code
Your radio is made by CLARION and the only CLARION code available for free (using a serial number ) from anywhere on the Internet is if your radio also has a BARCODE SERIAL NUMBER beginning with C7000000 + + + + on a label somewhere on the metal casing.
(There are usually two barcodes on one label. The one required is the lower one )
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If not then it will only be available from your Main Dealer or a Decoding Service
SOURCE: HI LOOKING FOR RADIO CODE FOR MY PEUGEOT 206
Visit http://www.radio-code.com/index.htm
Good luck.
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