You will have to copy the contents of the DVD-RW to your computer's hard drive. Then replace the DVD-RW with a blank DVD+-, and burn the contents you copied onto it using your burning software of the built in Windows burning software.
First, your PC should install DVD writer instead of DVD reader. Then you also need a DVD copy program to copy a DVD. For copying protected DVD, you can try Leawo DVD Copy which can decrypt the DVD protection and it can 1:1 DVD copy so that you can preserve the original DVD quality in the copy.
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