The power button is not the right button to press.
Here is the steps I take:
1. Power on the headset
2. Have PS3 scan for new devices
3. Hit the tiny button that is next to the volume buttons on the top of the headset.
4. PS3 should recognize "8860" and ask for a passkey which is "0000" by default
5. Paired and ready to go
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Usually answered in minutes!
Do you have the headset attached to the USB cable when trying to pair up
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