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Check to see the amount of water the iron requires. If too much is added it will spit water out can also come out of where the water goes in plus the holes the steam should come out. In order for the iron to steam the water must boil inside the iron. Check the instructions and see how mmuch the manufacturer suggests. You may have to fill it several times while doing the ironing. If there is no instruction try consulting the manufacturers web site for information on your make and model of iron. They should have instruction manuals available for download. If that is not the problem it could be cracked on the inside. Give the water adjustment a try first though a lot cheaper in the long run.
Fill it with a mix of 50% white vinegar and 50% water. Let it set for 30 minutes and steam it out for about 2 minutes. Unplug it and dump it. After it cools colpletely, fill it with water and steam it out. The rust is coming from your water supply, not the iron.
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