Microwaving cloth is not a good idea. Rather than drying out the moisture (or for whatever reason it was put in the oven), microwaving it will just make the water really, really hot! You could easily burn yourself trying to handle the item. The heat could also damage the fabric itself or even ignite it....which it looks like happened.
The microwave oven should be safe to use but you need to remove the odor.
A couple of ways to try to get rid of the burnt odor:
Fill a microwavable bowl with 1/2 cup water and 1 tablespoon white vinegar.
A different way is put two tablespoons of baking soda in a microwave safe bowl and add a cup of water on top of that. Then put the bowl in the microwave for three minutes. The baking soda will kill the funky smells and the water will start to steam clean the spots and stains.
Good luck with your troubleshooting.
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