I sense two different problems or one not completely described.
The followinbg would address the decoder issue.
It partially depends on what it is you're trying to play or how you like to hear it.
Check the Direct Mode Button and make sure it's not activated. (M on page 4).
Straight Mode (L on page 4) is a desirable starting point for multichannel material.
See page 24 of the manual to see all the things this beastie can do with all of the audio inputs.
http://www.retrevo.com/support/Yamaha-RX-V465-Receivers-manual/id/23270ag803/t/2/
Be advised that most commercial multichannel sound sources have been pre-mixed by the originators to provide an intended 'feel' and 'space', so modifying it might not be an improvement although it can provide a novel change. Like any spice, a little is best.
I find that processing 2-channel audio through the various DSP modes can make for some interesting and arguably pleasing effects.
If you 'search' the document for the word "decoder" it may lead you to a setting that's out of place.
"Not able to play music" should only happen if you have a source incorrectly chosen or the source is DTS and the decoder is off. Undecoded DTS will sound like high-level digital 'hash' noise because you're hearing the raw 'data' so it must be decoded to turn it into audio.
See the note on Page 2 regarding DTS-CD's then look at Page 33
I hope this was helpful.