As a modern car it will run fine on any unleaded gas/petrol and the engine will self-adjust it's ignition timing to suit.
But some Passat variants can additionally take advantage of Super Unleaded, it's a total waste of money and offer no benefits at all for most models. As you haven't given further details of your exact Passat variant I cannot be any more specific, but the recommended grade is usually on a label inside the tank filler door.
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