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Your problem is a faulty heater control valve. The design used on these vehicles allows for hot water to flow constantly and compete with the evaporator as there is no blender door. You have to replace the valve and possibly the control head. Meanwhile, you can bypass the valve to have cold air
The A/C system has a pressure switch will keep the A/C from running if the freon is low. It prevents damage to the A/C compressor from low freon.
My bet is you'll need to recharge the A/C system.
I know from experience that if the coolant is to low ( not just the freon levels in the compresor but the antifreeze/coolant level as well) the AC system will not cool and will blow hot. Check the coolant Antifreeze and freon levels, even with the Coolant being a little low my 1998 Ford E150 Van will blow hot. After you have ruled out of these possibilities and the chance it is the thermostat most likely the problem is what Ford calls the "Flap" it controls the air flow through the vent system when you switch from Heat to AC. When the Flap is working it closes off one systems air flow so as to not interfere with the current climate selection.
IF U ARE TRYIN TO GET THE HEAT U CAN DO 3 THINGS
1. TURN HEATER ON THE FACE/FEET POSITION AND PLACE ON HIGH, TAKE THE RADIATOR CAP OFF AND CONTINUE TO POUR WATER/COOLANT UNTIL HEAT GETS HOT
2. CHECK/REPLACE THERMASTAT
3. CHECK/REPLACE HEATER CORE
This is a redundancy thing in the climate control system. You'll want to take the console apart and check the connectors behind the climate control panel. I was installing a stereo in mine, and when I started the car (with the climate control disconnected), it did exactly what you're describing.
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