SOURCE: 99 cadillac de ville
the coolant temp sensor is at the rear of the engine and is a "bad word" to get to. the 3 relays are at the bottom,under the fans. if you remove the driver side fan out of the way( 2 10mm bolts holding the fan) you should have good access to them. they do have locks on them and may be tricky to unplug. there is a 7/16 nut holding the relay plate down. remove and it should be easy to remove them.
SOURCE: Location of coolant temperature sensor
Maybe this will help . although this is from a 1997 Caddy.
Cadillac DeVille Engine Coolant Temperature (ECT) Sensor Location
SOURCE: 2003 cadillac cts coolant temperature sensor
I cant find a pic of the loctation.
It is under the intake in the back in the coolant bridge it is not bad
to change if you are not affaid to take the intakes off but to get to
it you have to take the intake off
SOURCE: 1994 cadillac deville concours
On my car, which is the same as yours, it is located on the manifold top back left. Pictures in the book just show it on top.
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