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Immobilizers are designed to prevent what you are needing done. There is no easy way around it. Your best bet is to call a lock smith to cut you a new key and program it to work with your vehicle.
Looks the RFDI chip in the key is defect. Your Mercedes car dealer should be able to help you with that.
Fist to make sure it is a chip problem in the key and second by replacing the chip and the code and / or replacing the battery it an empty battery is the issue.
You sure its a V6?
The 190E 6cyl was an inline 6 and no I'm not aware of them having a chip. None of my 190E's or the 300E had a chip in the key. Not even my 92 S320
you can get uncut chipped keys from ekeylessremotes.com for around $16 to program them yourself however you will need 2 working keys if not you will have to have a dealer or a locksmith program the key for you.
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