I have a 88 chev v6 impounded scince 06 trying to
A TBI system should never have raw fuel poured down the butterfly. You state you had a fire, but without seeing it myself, I cannot gage the damage your vehicle might have suffered. That would depend on the size and duration of the fire, but to be safe, replace the injector assemblies. This is very easy to do on a TBI engine. Pouring fuel into a throttle body will not make the engine start drawing fuel from the tank; fuel is supplied to the engine fromt the tank by the electric fuel pump in the tank. A vehicle sitting unused and unsefviced for four years is going to have several fuel system problems, none of which can be repaired by a slug of gas in the TBI. By now, the fuel in your tank is bad, the fuel in the fuel pump is bad, the fuel in the lines is bad, the fuel in the fuel filter is bad, and the fuel in the injectors is bad. Gasoline is an organic product, not a chemical, and it has a shelf-life just like any food.
If you are sufficiently handy with tools, you will need to remove the fuel tank from your truck and empty all the old gas from it. Remove the fuel pump from the tank; disconnect the fuel lines from the throttle body and the vapor canister under the hood on the headlight bezel, remove and discard the old frame rail fuel filter and replace it with a new one (just remove it first--don't replace it until you have cleaned out the fuel lines with compressed air and a gas solvent), and remove and discard the old fuel injector assembly that sits atop the TBI like a spider. You will need a new one of these as well.
Have an automotive repair shop steam clean the tank. Using an air compressor with a nozzle gun, blow out all the fuel lines. At the minimum, you will have to clean the fuel pump with gas solvent repeatedly to remove all the sludge and varnish that forms in gasoline when left unused for lengthy periods of time, at worst, you will have to replace it as well.
When everything is clean and new as needed, re-assemble the fuel system, and put about two gallons of fresh new gasoline in the tank. (No more than two gallons; you may have to remove the tank again, and it won't be so heavy if you do not fill it.)
The Chevrolet fuel pump is self-priming but may take several seconds to prime and supply fuel to the engine.
You will also need to replace the spark plugs, plug wires, rotor and cap as a result of this long period of inactivity. Good luck; it can take some time to start a computer-controlled engine that has not been started in many years.